As an illustrative example, we apply the scheme to four-state Markovian models and Claisen rearrangement of allyl vinyl ether (AVE), and demonstrate that the reduced-dimensional representation ...

The allyl oleate ester was satisfactorily obtained under acid catalysis and it was used in compositions with styrene. The methodology used was able to show that the internal unsaturation of fatty ...

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Trost (Trost et al., 2003) reported a viable decarboxylative allyl etherification process that employed vinyl epoxides as allylic donors and 4-methoxybenzyl alcohol as an interceptor to produce ...

Using 1-heptyne as the starting material, the rearranged precursor allyl vinyl ether 31 was obtained through SN2 reaction, Lindlar reduction, deacetalization, and Grignard reagent coupling and ...

Nazarov assumed this involved acid-catalysed closure of the allyl vinyl ketone – now acting as a reaction intermediate. 6 He reported many further examples of divinylacetylene hydration–cyclisation to ...

Inverse-electron-demand Diels–Alder reactions have attracted intense research focus. However, enolate and enamine are the most employed intermediates to realize such transformation, and the use of ...

Hiersemann, M. and Abraham, L. (2001) The Cu (OTf)2- and Yb (OTf)3-Catalyzed Claisen Rearrangement of 2-Alkoxycarbonyl-Substituted Allyl Vinyl Ether. Organic Letters, 3, 49-52.

In this study, we tried to introduce a vinyl group into the structure of rosin monomer to synthesize rosin allyl ester. The ultraviolet (UV)-curing reaction of the rosin allyl ester was ...