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Start with intrinsic semiconductor – pure silicon (Si) or germanium (Ge). Add pentavalent dopant atoms: Examples: Phosphorus (P), Arsenic (As), Antimony (Sb) Each dopant atom has 5 valence electrons. Effect of doping: 4 electrons of the dopant form covalent bonds with neighboring Si atoms. The 5th electron is loosely bound → easily becomes a free electron. Result: Majority carriers: Electrons Minority carriers: Holes
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